Iron nanoparticles encapsulated within nitrogen and sulfur co-doped magnetic porous carbon as an efficient peroxymonosulfate activator to degrade 1 -naphthol

摘要

A novel iron nanoparticles encapsulated within nitrogen and sulfur co-doped magnetic porous carbon (Fe-N-S-MPC) was proposed by one-pot pyrolysis strategy to activate peroxymonosulfate (PMS) to degrade 1-naphthol using low-cost lignin as precursors. The Fe-N-S-MPC was characterized for structure and properties by different characterizations. The obtained materials had the morphology of iron nanoparticles encapsulated within nitrogen and sulfur co-doped magnetic porous carbon with rich functional groups and large specific surface area, which made the materials have a good catalytic property. It was proved that the doping of nitrogen and sulfur is pivotal for improving the catalytic performance. The radical quenching experiment confirmed that sulfate radical (SO_4~- •) and hydroxyl radical (OH·) are two major reactive oxygen groups. The reaction had phenomenon of the free radicals upsurge in the early stage and the shortage in the later stage. Therefore, a mathematical model was put forward to represent the two-stage reaction kinetics. By adding oxidants in batches, the degradation effect could reach nearly 100% within 30 min. The Fe-N-S-MPC were applied to the degradation of 1 -naphthol in soil and showed high degradation performance. This work provided a new type of catalytic material by the high-value utilization of waste for the degradation of organic pollutants.