Insights into the anthropogenic load and occupational health risk of heavy metals in floor dust of selected workplaces in an industrial city of Iran

摘要

The levels of Cd, Cr. Cu, Fe, Mn, Pb and Zn were determined in floor dusts from mechanical (MRWs) and battery repairing workshops (BRWs) in Yazd, Iran. The study aimed to evaluate the anthropogenic contribution to the presence of heavy metals (HMs), the possible sources and the related risks that could arise from occupational exposure in the studied workplace microenvironments. Among the analyzed heavy metals, Cu, Pb and Zn exhibited enhanced concentrations in the floor dusts. The EF calculations showed an extremely severe enrichment of HMs, especially for Cd, Cu and Pb, while floor dusts were characterized as "extremely polluted" with regards to those metals. In any case, both EF and I_(geo) values were significantly higher in the BRWs. These results were also supported by NIPI and PLI values, while contour maps of PU values in both MRWs and BRWs outlined workshops in N-NE part of Yazd as more impacted compared to other spatial locations. Principal component analysis (PCA) and Pearson's correlation outscored workshops activities as the principal sources of heavy metals. The health risk assessment suggested considerable non-carcinogenic risks regarding Pb in the BRWs which exhibited HQ_(ing) (mean 2.91) and HI (mean 3.03) values higher than safe level. Regarding carcinogenic risks, CR values for both Cd and Cr were below the safe level (1.0 × 10~(-6)). The occupational exposure to Pb was evaluated through the predicted BLL values, where with averages of 3.33 μg/dl and 21.4 μg/dl for MRWs and BRWs workers, respectively, indicated a severe Pb exposure for BRWs workers.