A new proposal for the determination of polychlorinated biphenyls in environmental water by using host-guest adsorption

摘要

Polychlorinated biphenyls (PCBs) are ubiquitous environmental pollutants whose wide industrial use has been banned over the years in most countries due to their persistence and bioaccumulation. In fact, the International Agency for Research on Cancer defined them in 2016 as carcinogenic to humans based on sufficient evidence of an increased risk of cancer, being children and pregnant or lactating women the most vulnerable population subgroups. In this work, a new alternative for the determination of polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB138, PCB153, and PCB180) in water samples has been developed by using a cyclodextrin-containing silica microparticulated material as an adsorbent in solid-phase extraction. Gas chromatography coupled to an electron capture detector has been used in the quantification step. The methodology allows quantifying polychlorinated biphenyls at very trace levels, with limits of detection between 0.2 and 1.7 ng L~(-1). Other parameters such as the repeatability, with coefficients of variation lower than 11%, were likewise established. To end, real water samples were analyzed, and the results were comparable with those obtained with a reference method. The proposed methodology can be utilized for assessing the presence of these compounds in the environment and can come in handy for evaluation and remediation purposes.