Bio-inspired anchoring of amino-functionalized multi-wall carbon nanotubes (N-MWCNTs) onto PES membrane using polydopamine for oily wastewater treatment

摘要

The major problem that limits the utilization of PES membranes in treatment of oily wastewater is the drastic irreversible membrane fouling due to the attachment of oil droplets onto the membrane surface. The goal of this study was to develop a novel, fast and facile post-functionalization of polydopamine (PDA) coated membranes using pre-synthesized nanoparticles for fabrication of novel organic-inorganic hybrid recoverable membranes with high hydrophilicity and underwater oleophobicity. Here, bio-inspired technique was studied because the membrane technology could separate small oil droplets (even <10μm) with high performance if faced little fouling phenomena during the treatment process. The amino-functionalized multi-wall carbon nanotubes (N-MWCNTs) were anchored onto the PDA coated PES membranes. The membranes characteristics, with specific focus on surface morphology and wettability were investigated. The newly developed PES/PDA/N-MWCNTs membranes showed an enhanced flux (~1086%) compared to the unmodified PES membrane. This enhancement was attributed to the high hydrophilic and underwater oleophobic properties, which were found to alleviate the effect of fouling. The total fouling ratio (Rt) of the PES/PDA/N-MWCNTs membrane was 22.35%, which was far lower than that of the unmodified PES membrane (98.38%). Meanwhile, most of the fouling was reversible for the former with the remaining (irreversible fouling) of 18.08%. It was concluded that cake filtration is the dominant fouling mechanism of the PES/PDA/N-MWCNTs membranes due to their average pore diameter. The modified membranes showed high oil rejection (>99%) so that the obtained clean water with oil concentration lower than 5 ppm met the wastewater discharge standard recommendations. Also, evaluation of the PES/PDA/N-MWCNT membrane in cross-flow filtration showed its antifoul-ing properties in the long-term application (16 h).