Activation Energy of the Low-Load NaCl Transition from Nanoindentation Loading Curves

摘要

Access to activation energies E-a of phase transitions is opened by unprecedented analyses of temperature dependent nanoindentation loading curves. It is based on kinks in linearized loading curves, with additional support by coincidence of kink and electrical conductivity of silicon loading curves. Physical properties of B1, B2, NaCl and further phases are discussed. The normalized low-load transition energy of NaCl (W-trans/mu N) increases with temperature and slightly decreases with load. Its semi-logarithmic plot versus T obtains activation energy E-a/mu N for calculation of the transition work for all interesting temperatures and pressures. Arrhenius-type activation energy (kJ/mol) is unavailable for indentation phase transitions. The E-a per load normalization proves insensitive to creep-on-load, which excludes normalization to depth or volume for large temperature ranges. Such phase transition E-a/mu N is unprecedented material's property and will be of practical importance for the compatibility of composite materials under impact and further shearing interactions at elevated temperatures. SCANNING 36:582-589, 2014. (c) 2014 Wiley Periodicals, Inc.