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Detailed modelling of biomass steam gasification in a dual fluidized bed gasifier with temperature variation

机译:具有温度变化的双流化床气化炉中生物质蒸汽气化的详细模型

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摘要

The modelling of biomass gasification enables the optimization of the process designs, but it is a challenge due to its high complexity. Here a model for prediction of the performance of a 100-kW dual bed fluidized biomass gasifier is derived and implemented in the ASPEN plus environment. Detailed pyrolysis modelling is properly addressed, and this is believed to be a key factor of this approach and enables more accurate results. The proposed model and its basic assumptions were extensively validated on a range of operating temperature by conducting experiments using softwood pellets as fuel and fresh olivine sand as bed material. The impact of the gasifier temperature variation on the final product gas composition is measured in the experiments and used to tune the model to have a better insight on the pyrolysis process, the char heterogeneous reactions as well as the deviation from equilibrium of the water gas shift reaction. After the assessment phase, the model was applied to to the simulation of a real case experiments and measured gas yields. The results can be considered appropriate and the difference between prediction and measurement of H-2, CO and CO2 are lower than 10%, while CH4/C2H4 show values that are slightly higher than 10%. (C) 2019 Elsevier Ltd. All rights reserved.
机译:生物质气化的建模可以优化工艺设计,但是由于其复杂性很高,这是一个挑战。在此,在ASPEN plus环境中导出并实现了一个用于预测100 kW双床流化生物质气化炉性能的模型。适当解决了详细的热解建模问题,据信这是该方法的关键因素,可实现更准确的结果。通过使用软木颗粒作为燃料和新鲜的橄榄石砂作为床层材料进行实验,在一定的工作温度范围内对提出的模型及其基本假设进行了广泛验证。在实验中测量了气化炉温度变化对最终产物气体成分的影响,并用于调整模型,以更好地了解热解过程,炭的非均相反应以及水煤气转换平衡的偏差。反应。在评估阶段之后,将模型应用于真实案例实验的模拟和测量的气体产量。结果可以认为是适当的,H-2,CO和CO2的预测和测量值之间的差异小于10%,而CH4 / C2H4的显示值略高于10%。 (C)2019 Elsevier Ltd.保留所有权利。

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