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"The Effect of Solder Paste Reflow Conditions on Surface Insulation Resistance" Three different reflow temperature vs. time profiles - a 1.5℃/s ramp to 230℃, a 1.5℃/s ramp to 250℃ and a 90s soak at 175℃ with a 230℃ peak - were used to reflow three lead-free solder pastes in air and nitrogen atmospheres. Fourier transform IR spectra of the reflowed flux residues show how reflow profile conditions and atmosphere affects the decrease of a peak around 1700 cm~(-1) and the appearance and increase of another peak at 1600 cm~(-1). The 1700 cm~(-1) is smaller for flux residues reflowed under hotter conditions and for those reflowed in air. The peak at 1600 cm~(-1) is larger for residues exposed to hotter reflow profiles in air, but is hardly present for residues reflowed in nitrogen. The effect of these reflow conditions on surface insulation resistance per IPC-TM-650 Method 2.6.3.7 at 40℃/90% RH and 12V bias has been studied. This measurement shows that hotter reflow conditions result in higher SIR values for two of the pastes, as would be expected, but has a smaller affect on the third paste.
机译:“焊膏回流条件对表面绝缘电阻的影响”三种不同的回流温度随时间变化的曲线-1.5℃/ s上升至230℃,1.5℃/ s上升至250℃,以及在175℃下90s均热峰值温度为230℃-用于在空气和氮气气氛中回流三种无铅焊膏。回流焊剂残渣的傅立叶变换红外光谱表明回流条件和气氛如何影响1700 cm〜(-1)附近一个峰的减少以及1600 cm〜(-1)附近另一个峰的出现和增加。对于在较热条件下回流的助焊剂残渣和在空气中回流的助焊剂残渣,1700 cm〜(-1)较小。对于暴露于空气中较热回流曲线的残留物,在1600 cm〜(-1)处的峰较大,而对于氮中回流的残留物则几乎不存在。根据IPC-TM-650方法2.6.3.7在40℃/ 90%RH和12V偏压下研究了这些回流条件对表面绝缘电阻的影响。该测量结果表明,较热的回流条件导致其中两种焊膏的SIR值较高,这与预期的一样,但对第三种焊膏的影响较小。

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