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Preparation and Morphology of High-Performance Exfoliated Poly(sodium acrylate)/Hydrotalcite Nanocomposite Superabsorbents

机译:高性能片状聚丙烯酸钠/水滑石纳米复合高吸水剂的制备与形貌

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摘要

A poly-matrix composite - poly(sodium acrylate) (PSA)/hydrotalcite (HT) (PSA/HT) nanocomposite superabsorbent - with obvious improvements in both the water absorbency and salt absorbency has been prepared by the intercalated HT, using sodium methyl allyl sulfonate as an intercalation agent. The superabsorbents acquired their highest water (salt) absorbency when the content of HT is 3 wt%. The highest absorbency for deionized water and 0.9 wt% NaCl ^sub (aq)^ were 1100 g/g and 145 g/g, respectively. Microstructures were analyzed by X-ray diffraction and scanning electron microscope. Chemical analysis was determined measurements. Results showed that HT incorporated into the superabsorbents was by Fourier infrared spectroscopy and energy dispersion spectroscopy. Results showed that the superabsorbent particles were in the form of spheres, and the hydrogels were in the form of regular network structures. [PUBLICATION ABSTRACT]
机译:一种多基复合材料-聚丙烯酸钠(PSA)/水滑石(HT)(PSA / HT)纳米复合超强吸收剂-插层HT使用甲基烯丙基钠制备了吸水率和盐吸收率均有明显改善的材料磺酸盐作为插层剂。当HT的含量为3wt%时,超吸收剂获得最高的水(盐)吸收性。去离子水和0.9 wt%NaCl ^ sub(aq)^的最高吸收率分别为1100 g / g和145 g / g。通过X射线衍射和扫描电子显微镜分析微观结构。化学分析是确定的测量值。结果表明,通过傅立叶红外光谱和能量色散光谱法将HT掺入超吸收剂中。结果表明,超吸收颗粒呈球形,水凝胶呈规则网络结构。 [出版物摘要]

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    《Polymer Engineering and Science》 |2009年第2期|p.264-271|共8页
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    Yatao Zhang, Lihai Fan, Lihua Cheng, Lin Zhang, Huanlin ChenCollege of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027,Zhejiang, People's Republic of ChinaCorrespondence to: L. Zhang, e-mail: linzhang@zju.edu.cnContract grant sponsor: National Natural Science Foundation of China: contract grant numbers: 20576114, 20776123.DOI 10.1002/pen.21252Published online in Wiley InterScience (www.interscience.wiley.com).© 2008 Society of Plastics Engineers,;

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