Preparation and Interaction Characteristics of Exfoliated ABS/Organoclay Nanocomposite

摘要

A series of poly(acrylonitrile-co-butadiene-co-styrene) (ABS)/organoclays (Cloisite10A, Cloisite25A, and Cloisite30B) nanocomposites are prepared via two different methods: one is a solution blending and the other is a two-step process where the solution blended mixture is subsequently compounded in the melt state using a torque rheometer (SOAM method). The effect of surfactants on the surface of three different organoclays that are modified with alkylammonium salts in polymer/ organoclay nanocomposites is investigated by focusing on two major aspects; Flory-Huggins interaction parameters and physical (thermal and mechanical) properties. The d-spacing of both neat organoclays and intercalated/exfoliated organoclays is examined by X-ray diffraction analysis, and the microstructure of these nanocomposites is examined by FE-TEM. Solubility parameters of both polymer and organoclays of interest are calculated according to the group contribution method. Viscoelastic behavior of the nanocomposites is also investigated by measuring rheological properties under an oscillatory shear. The increase in the onset temperature of the thermal degradation indicates the enhancement of thermal stability of ABS due to intercalation or partial exfoliation. Mechanical properties, such as, tensile strength, tensile modulus, and elongation at break of the nanocomposites are measured. [PUBLICATION ABSTRACT]