Studies of synergism between carbon black and stabilisers in LDPE photodegradation

摘要

The interaction between two commercial hindered piperidine compounds, three commercial antioxidants, a secondary anti- oxidant and two types of furnace carbon black (CB) (with a different surface area and surface chemistry) in the photo-oxidation of LDPE film have been studied using FTIR infrared spectroscopy. The nature of stabiliser-CB interactions has also been analysed through the use of flow microcalorimetry. The stabilisers used are, a commercial polymeric HALS, namely Chimassorb 944(r), and Tinuvin 622(r) LD(r), primary and secondary antioxidants, namely Irganox 1010(r) and Irganox 1076(r), Cyandx 1790(r) and Irgafos 168(r). For the fillers, two carbon blacks were chosen with different features as the specific surface particle size and chemistry. During photo-oxidation the interactions are variable, being both antagonistic and synergistic. Generally for the primary anti- oxidants alone their photostabilising effects on the polymer film are low or negligible and can be related to the stability of the additives. However, in the presence of a hindered piperidine light stabiliser no such correlations between polymer and antioxidant stability exist. In most of the cases, antagonistic interactions were found between HALS and the antioxidants. Differences in the performance of the polymeric type of HALS were evidenced, as well as between the CB grades. Less antagonism was found between primary and secondary antioxidants with CB for two-additive formulations. This effect is overcome by a powerful synergistic interaction in three additive formulations. Antagonism was found between one HALS and CB. It is concluded that the nature of the CB plays an important role in controlling their performances as a stabilising agent alone, as well as their interactions with light stabilisers and antioxidants.