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High mechanical strength and stability of alginate hydrogel induced by neodymium ions coordination

机译:钕离子配位诱导的藻酸盐水凝胶的高机械强度和稳定性

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摘要

An alginate-based, stable and high mechanical strength hydrogel was fabricated by trivalent ions coordination in the presence of neodymium Ions. The chemical components and morphology of the hydrogel were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The effects of pH values on the swelling properties of hydrogels were investigated as it reveals that the pH values have an obvious effect on the swelling ratio. The as-prepared hydrogel exhibited high compressive strength and stability, which is much higher than that of the alginate hydrogel formed by Ca~(2+) ionic cross-linked. Moreover, the Nd(Ⅲ)-Alg hydrogel also exhibited the properties of fluorescence. The easy and fast fabrication, outstanding mechanical and stable properties indicated the hydrogel as a promising material that can be used in cartilage tissue.
机译:在钕离子存在下,通过三价离子配位制得了基于藻酸盐的,稳定且高机械强度的水凝胶。通过傅立叶变换红外光谱(FTIR),X射线光电子能谱(XPS)和扫描电子显微镜(SEM)表征了水凝胶的化学成分和形态。研究了pH值对水凝胶溶胀性能的影响,因为它表明pH值对溶胀率具有明显的影响。所制备的水凝胶具有较高的抗压强度和稳定性,远高于由Ca〜(2+)离子交联形成的藻酸盐水凝胶的抗压强度和稳定性。此外,Nd(Ⅲ)-Alg水凝胶还表现出荧光性质。易于制造,快速制造,出色的机械性能和稳定性能表明水凝胶是一种可用于软骨组织的有前途的材料。

著录项

  • 来源
    《Polymer Degradation and Stability》 |2016年第11期|1-7|共7页
  • 作者单位

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

    School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, Jiangsu Province, 211189, PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Alginate; Hydrogel; Stability; Lanthanide ions; Coordination;

    机译:海藻酸盐;水凝胶;稳定性;镧系离子;协调;

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