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首页> 外文期刊>Physical review letters >Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water
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Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water

机译:深度冷却的承压水中的玻色子峰:探索水中液-液过渡存在的一种可能方法

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摘要

The boson peak in deeply cooled water confined in nanopores is studied with inelastic neutron scattering. We show that in the (P, T) plane, the locus of the emergence of the boson peak is nearly parallel to the Widom line below ~1600 bar. Above 1600 bar, the situation is different and from this difference the end pressure of the Widom line is estimated. The frequency and width of the boson peak correlate with the density of water, which suggests a method to distinguish the hypothetical "low-density liquid" and "high-density liquid" phases in deeply cooled water.
机译:利用非弹性中子散射研究了被限制在纳米孔中的深冷水中的玻色子峰。我们发现在(P,T)平面上,玻色子峰的出现轨迹几乎平行于〜1600 bar以下的Widom线。高于1600 bar,情况就不同了,根据这一差异,可以估算Widom管线的最终压力。玻色子峰的频率和宽度与水的密度相关,这提示了一种区分深冷水中假想的“低密度液体”和“高密度液体”相的方法。

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  • 来源
    《Physical review letters》 |2014年第23期|237802.1-237802.5|共5页
  • 作者单位

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA,Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan, Republic of China;

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;

    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA;

    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA;

    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA,Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA;

    Spoliation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA;

    Spoliation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA;

    Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Republic of China;

    Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    time-dependent properties; relaxation;

    机译:时间相关的属性;松弛;

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