Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.0~(2,7)]undec-3-ene to endo-Tricyclo[5.2.2.0~(2,6)]undec-8-ene

John E.Baldwin; Andrew R.Bogdan; David C.Powers; Phyllis A.Leber

首页> 外文期刊>Organic letters >Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.0~(2,7)]undec-3-ene to endo-Tricyclo[5.2.2.0~(2,6)]undec-8-ene

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Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.0~(2,7)]undec-3-ene to endo-Tricyclo[5.2.2.0~(2,6)]undec-8-ene

机译：顺，反，顺-三环[6.3.0.0〜（2,7）]十一碳-3-烯的热异构化为内三环[5.2.2.0〜（2,6）]十一碳-8-烯的热异构化

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The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.0~(2,7)]undec-3-ene (1) to endo-tricyclo[5.2.2.0~(2,6)]undec-8-ene (2) at 315degC occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway.

机译：顺，反，顺-三环[6.3.0.0〜（2,7）]十一碳-3-烯（1）的气相热异构化为内三环[5.2.2.0〜（2,6）]十一碳- 315°C下的8-ene（2）通过对称禁止的[1,3]表面，保留（sr）途径干净地发生。

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《Organic letters》 |2005年第23期|p.5195-5197|共3页
作者
John E.Baldwin; Andrew R.Bogdan; David C.Powers; Phyllis A.Leber;
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作者单位

Department of Chemistry,Syracuse University,Syracuse,New York 13244,and Department of Chemistry,Franklin and Marshall College,Lancaster,Pennsylvania 17604;

Department of Chemistry,Syracuse University,Syracuse,New York 13244,and Department of Chemistry,Franklin and Marshall College,Lancaster,Pennsylvania 17604;

Department of Chemistry,Syracuse University,Syracuse,New York 13244,and Department of Chemistry,Franklin and Marshall College,Lancaster,Pennsylvania 17604;

Department of Chemistry,Syracuse University,Syracuse,New York 13244,and Department of Chemistry,Franklin and Marshall College,Lancaster,Pennsylvania 17604;

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正文语种 eng
中图分类有机化学;
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1. Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.0~(2,7)]undec-3-ene to endo-Tricyclo[5.2.2.0~(2,6)]undec-8-ene [J] . John E.Baldwin, Andrew R.Bogdan, David C.Powers, Organic letters . 2005,第23期

机译：顺，反，顺式三环[6.3.0.0〜（2,7）]十一碳-3-烯的热异构化为内三环[5.2.2.0〜（2,6）]十一碳-8-烯的热异构化
2. Thermal isomerizations of cis,anti,cis-tricyclo[6.4.0.02,7]dodec-3-ene to trans- and cis,endo-tricyclo[6.2.2.02,7]dodec-9-ene: diradical conformations and stereochemical outcomes in [1,3] carbon shifts [J] . Phyllis A. Leber, Andrew R. Bogdan, David C. Powers, Tetrahedron . 2007,第27期

机译：顺式，反式，顺式-三环[6.4.0.02,7] dodec-3-烯的热异构化为反式和顺式，内-三环[6.2.2.02,7] dodec-9-ene的双自由基构型和立体化学结果[1,3]碳转移
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Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.0~(2,7)]undec-3-ene to endo-Tricyclo[5.2.2.0~(2,6)]undec-8-ene

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