Efficient co-sensitization of dye-sensitized solar cells by novel porphyrin/triazine dye and tertiary aryl-amine organic dye

摘要

A novel porphyrin dye ZnP-triazine-(gly)_2, consisting of a zinc-metallated porphyrin unit covalently linked through its peripheral aryl-amino group with a 1,3,5-triazine group which is functionalized by two carboxylic acid groups of glycine moieties, has been synthesized. Photophysical and electrochemical measurements, as well as theoretical DFT calculations, suggest that the compound exhibits appropriate light absorption characteristics and frontier molecular orbital levels for use as sensitizer in dye-sensitized solar cells (DSSCs). The ZnP-triazine-(gly)_2 based solar cell was found to exhibit a power conversion efficiency (PCE) value of 4.72%. A significant improvement of the overall photovoltaic efficiency of the solar cell was achieved up to 7.34% upon co-sensitization with a tertiary aryl-amine D with two ethynyl-pyridine substituents and cyano-acetic acid anchoring group, which exhibits complementary light absorption characteristics with the porphyrin dye. The higher PCE value of the co-sensitized solar cell is attributed to its enhanced short circuit current (J_(sc)), which is due to improved light harvesting efficiency, reduced porphyrin aggregation, and faster electron injection and charge collection, as well as its enhanced open circuit voltage (V_(oc)), which is due to increased electron density in the TiO_2 conduction band of the photoanode. These results are in accordance with electrochemical impedance spectra (EIS) of the solar cells, which revealed higher charge recombination resistance (R_(rec)). longer electron lifetime (τ_e), and shorter electron transport time (τ_d) for the co-sensitized solar cell.