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Aromatic C-H amination: a radical approach for adding new functions into biology- and materials-oriented aromatics

机译:芳香族C-H胺化:一种向生物学和材料导向的芳族化合物添加新功能的根本方法

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摘要

C-H amination is the most powerful method to directly add nitrogen functionalities into a variety of arenes including biology- and materials-oriented molecules. Recent developments in aromatic C-H amination chemistry have enabled the conversion of unactivated arenes into a range of arylamine derivatives without using directing groups or excess amounts of arenes. The key for such successful transformations is the catalytic generation of nitrogen or arene radical intermediates. In this perspective, we discuss recent developments in the radical C-H amination of aromatic molecules. We believe the resulting arylamines, which are hitherto difficult to access, will exhibit unexplored functions for biological and materials application.
机译:C-H胺化是将氮官能团直接添加到各种芳烃(包括面向生物和材料的分子)中的最有效方法。芳族C-H胺化化学的最新进展已使未活化的芳烃转化为一系列芳胺衍生物,而无需使用直接基团或过量的芳烃。这种成功转化的关键是氮或芳烃自由基中间体的催化生成。从这个角度出发,我们讨论了芳香族分子自由基C-H氨基化的最新进展。我们相信,迄今难以获得的所得芳基胺在生物和材料应用方面将展现出未开发的功能。

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  • 来源
    《Organic & biomolecular chemistry》 |2017年第29期|6071-6075|共5页
  • 作者单位

    Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan;

    Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan;

    Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan,JST, ERATO, Itami Molecular Nanocarbon Project, Nagoya University, Chikusa, Nagoya 464-8602, Japan;

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