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Temperature-dependence on the structural, optical, and magnetic properties of Al-doped ZnO nanoparticles

机译:温度依赖于Al掺杂的ZnO纳米颗粒的结构,光学和磁性

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摘要

Al-doped ZnO nanoparticles synthesized by a hydrothermal method at relatively low temperature synthesis and anneal were reported in this paper. The XRD results reveal that all the samples have a hexagonal wurtzite structure. A higher synthesis temperature leads to a slight increase in the grain size and improvement of the crystal quality. Different morphologies evolved from acicular closely-packed morphology to dandelion-like 3D nanostructures can be obtained by controlling the synthesis temperatures. Moreover, the influence of synthesis temperature on optical property indicates that the absorption ability in ultraviolet region declines with increasing the synthesis temperature. In addition, the annealed nanoparticles have an enhancement of the room temperature ferromagnetism (RT-FM) and the saturation magnetization (M-S). Those results suggest that Al-doped ZnO nanoparticles synthesized at relatively low temperature could be a promising candidate for photosensitive and room temperature nanolasers applications. (C) 2016 Elsevier B.V. All rights reserved.
机译:本文报道了在较低的温度下通过水热法合成并退火的铝掺杂ZnO纳米粒子。 XRD结果表明,所有样品均具有六方纤锌矿结构。较高的合成温度导致晶粒尺寸略微增加并改善了晶体质量。通过控制合成温度可以获得从针状紧密堆积形态到蒲公英状3D纳米结构的不同形态。此外,合成温度对光学性能的影响表明,随着合成温度的升高,紫外线区域的吸收能力下降。另外,经退火的纳米颗粒具有增强的室温铁磁(RT-FM)和饱和磁化强度(M-S)。这些结果表明,在相对较低的温度下合成的Al掺杂的ZnO纳米粒子可能是光敏和室温纳米激光应用的有前途的候选者。 (C)2016 Elsevier B.V.保留所有权利。

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