首页> 外文期刊>Ofioliti >INVESTIGATION OF SILICATE MICRO-INCLUSIONS FROM ORHANELI AND HARMANCIK CHROMITITES (NW TURKEY): NEW ULTRAHIGH-PRESSURE EVIDENCE FROM WESTERN TETHYAN OPHIOLITIC CHROMITITES
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INVESTIGATION OF SILICATE MICRO-INCLUSIONS FROM ORHANELI AND HARMANCIK CHROMITITES (NW TURKEY): NEW ULTRAHIGH-PRESSURE EVIDENCE FROM WESTERN TETHYAN OPHIOLITIC CHROMITITES

机译:Orhaneli和Harmancik铬铁矿(西北土耳其)中硅酸盐微量元素的研究:西部Tethyan蛇绿铬铁矿的超高压证据

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摘要

In this study, mainly silicate and some sulfide micro-inclusions hosted in magnesiochromites of chromitites from Orhaneli Ophiolite Complex and Har-mancik Peridotites in northwestern Turkey are studied. Existence of randomly distributed anhedral (globular), selectively oriented lamellareedle-shaped silicate micro-inclusions and several other cubic/octahedral inclusions hosted in magnesiochromites are noted along with Ir-group platinum-group element (IPGE) bearing phases and base metal sulfides (BMS). The microscopic observations, Raman, electron dispersive and wavelength dispersive spectrometry data have shown that the randomly distributed anhedral (globular) silicate inclusions mainly consist of forsterite and diopside. Selectively oriented lamellareedle-shaped silicate micro-inclusions are determined as diopsides. Some of the cubic/octahedral inclusions are identified as (cubic) Mg-silicates, while some other inclusions are identified as euhedral to subhedral clinopyroxene and Na-K-Ca and Mg bearing silicates. An important amount of the studied cubic/octahedral inclusions are identified as negative crystals of cubic/octahedral form (some in form of trigonal or made crystals). The oriented lamellaeeedles of diopside are found both in the Orhaneli and Harmancik chromitites. Cubic/octahedral Mg-silicates and negative crystals are only detected in a multi-textured chromitite sample (with dunitic-orbicular, semi-massive and massive textures), which lacks the oriented diopside lamellaeeedles. Although no other ultra-high-pressure (UHP) phases are found, the existence of oriented diopside lamellaeeedles in the Orhaneli and Harmancik chromitites are interpreted as the first in-situ evidence of UHP conditions and possibly their deep mantle recycling history. It may be speculated that the occurrence of micro-lamellaeeedles of diopside in the Orhaneli chromitites within the cumulate dunites result from entrapment of recycled relics of UHP chromitites within the upwelling primordial melts that replenished the evolved magmas ponding in the MTZ. A step-by-step textural interpretation of the multi-textured Harmancik chromitite sample also suggested at least two stages of chromite formation, the former represented with the tightly packed nodular chromite nuclei within the dunitic orbicules, and the latter with surrounding semi-massive to massive (tightly packed) chromitites. The former stage can clearly be traced to be finally incorporated within the latter. The cubic/octahedral Mg-silicates and negative crystals are both seen within the first stage chromitite nuclei of the dunitic orbicules and the second stage surrounding chromitite. Occurrences of these inclusions are also questioned for a possible link between the textural evolution of chromitite and the UHP processes, and possibilities for finding a field (macroscopic) evidence for discriminating UHP chromitites. Due to some conflicting findings, it is concluded that more data are needed for reaching a final decision.
机译:在这项研究中,主要研究了位于土耳其西北部Orhaneli Ophiolite配合物和Har-mancik橄榄岩的铬铁矿的镁铬铁矿中的硅酸盐和一些硫化物微夹杂物。注意到存在于镁铬铁矿中的随机分布的无规面状(球状),定向取向的层状/针状硅酸盐微夹杂物和其他几种立方/八面体夹杂物以及含Ir-铂族元素(IPGE)的相和贱金属硫化物(BMS)。显微观察,拉曼光谱,电子色散和波长色散光谱数据表明,无规分布的无规(球状)硅酸盐夹杂物主要由镁橄榄石和透辉石组成。将选择性取向的层状/针状硅酸盐微夹杂物确定为透辉石。某些立方/八面体夹杂物被鉴定为(立方)Mg硅酸盐,而其他一些夹杂物被鉴定为对亚面斜向辉石和Na-K-Ca和含Mg硅酸盐的表面。大量研究的立方/八面体夹杂物被确定为立方/八面体形式的负晶体(某些呈三角形或人造晶体形式)。在Orhaneli和Harmancik铬铁矿中均发现了透辉石的定向片/针。立方/八面体的Mg硅酸盐和负晶体仅在多结构的铬铁矿样品(具有双圆形,半质量和块状结构)中检测到,该样品缺少定向的透辉石片/针。尽管未发现其他超高压(UHP)相,但Orhaneli和Harmancik铬铁矿中定向透辉石片晶/针的存在被解释为UHP条件的第一个原位证据,也可能是其深层地幔循环历史的证据。可以推测,堆积块体中Orhaneli铬铁矿中透辉石微片/透辉石针的出现是由于回收的UHP铬铁矿遗留在上升流的原始熔体中,从而补充了MTZ中沉积的岩浆。对多纹理Harmancik铬铁矿样品的逐步纹理解释还表明,至少有两个阶段的铬铁矿形成,前者以双立体小球内紧密堆积的球状铬铁矿核为代表,而后者则围绕着半大质量的铬铁矿。块状(紧密包装)铬铁矿。可以明确地追溯到前一个阶段,最终将其并入后者。立方/八面体的Mg-硅酸盐和负晶体都在双稳态小球的第一阶段铬铁矿核内和第二阶段围绕铬铁矿的内层中均可见。还质疑这些夹杂物的出现,以将铬铁矿的组织演化与UHP过程之间的可能联系,以及发现用于区分UHP铬铁矿的现场(宏观)证据的可能性。由于发现有些矛盾,因此得出结论,需要更多数据才能做出最终决定。

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