PERFORMANCE OF THORIUM-BASED MIXED-OXIDE FUELS FOR THE CONSUMPTION OF PLUTONIUM IN CURRENT AND ADVANCED REACTORS

摘要

A renewed interest in thorium-based fuels has arisen lately based on the need for proliferation resistance, longer fuel cycles, higher burnup, and improved waste form characteristics. Recent studies have been directed toward homogeneously mixed, heterogeneously mixed, and seed-and-blanket thorium-uranium oxide fuel cycles that rely on "in situ" use of the bred-in ~(233)U. However, due to the higher initial enrichment required to achieve acceptable burnups, these fuels are encountering economic constraints. Thorium can nevertheless play a large role in the nuclear fuel cycle, particularly in the reduction of plutonium inventories. While uranium-based mixed-oxide (MOX) fuel will decrease the amount of plutonium in discharged fuel, the reduction is limited due to the breeding of more plutonium (and higher ac-tinides) from the ~(238)U. Here, we present calculational results and a comparison of the potential burnup of a thorium-based and uranium-based mixed-oxide fuel in a light water reactor. Although the uranium-based fuels outperformed the thorium-based fuels in achievable burnup, a depletion comparison of the initially charged plutonium (both reactor and weapons grade) showed that the thorium-based fuels outperformed the uranium-based fuels by more that a factor of 2, where >70% of the total plutonium in the thorium-based fuel is consumed during the cycle. This is significant considering that the achievable burnups of the thorium-based fuels were 1.4 to 4.6 times less than the uranium-based fuels for similar plutonium enrichments. For equal specific burnups of ～60 MWd/kg (i.e., using variable plutonium weight percentages to give the desired burnup), the thorium-based fuels still outperform the uranium-based fuels by more than a factor of 2, where the total plutonium consumption in a three-batch, 18-month cycle was 60 to 70%. This is fairly significant considering that 10 to 15% (by weight) more plutonium is needed in the thorium-based fuels as compared to the uranium-based fuels to achieve these burnups. Furthermore, thorium-based fuels could also be used as a strategy for reducing the amount of long-lived nu-clides (including the minor actinides) and thus the ra-diotoxicity in spent nuclear fuel. Although the breeding of ~(233)U is a concern, the presence of ~(233)U and its daughter products (namely ~(208)Tl) can aid in making this fuel self-protecting, and/or enough ~(238)U can be added to denature the fissile uranium. From these calculations, it appears that thorium-based fuel for plutonium incineration is superior when compared to uranium-based fuel and should be considered as an alternative to traditional MOX in both current and future/advanced reactor designs.