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Multiwalled carbon nanotubes-magnetite reinforced thermoplastic polypropylene- natural rubber blends

机译:多壁碳纳米管-磁铁矿增强热塑性聚丙烯-天然橡胶混合物

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摘要

The effect of multiwalled carbon nanotubes (MWCNTs)-magnetite (Fe_3O_4) hybrid content on the magnetic and dynamic mechanical properties of thermoplastic polypropylene-natural rubber (TPNR) nanocomposites was evaluated. The effect of acid treatment of MWCNTs on the properties of nanocomposites has also been examined. TPNR/fillers nanocomposites were prepared via a Thermo Haake internal mixer using melt blending method with ball-milling technique as a pre-mixed process. The acid treatment successfully shortened the lengths and disentangled the crowds of MWCNTs. The improved dispersion of acid-treated MWCNTs-Fe_3O_4 in TPNR matrix and the enhanced interfacial adhesion between acid-treated MWCNTs-Fe_3O_4 and TPNR matrix increased the magnetic and dynamic mechanical properties. Acid-treated MWCNTs-Fe_3O_4 filled TPNR shows 10% improvement in storage modulus over neat TPNR due to the fine dispersion of MWCNTs in the TPNR matrix.
机译:评估了多壁碳纳米管(MWCNTs)-磁铁矿(Fe_3O_4)杂化含量对热塑性聚丙烯-天然橡胶(TPNR)纳米复合材料的磁性和动态力学性能的影响。还检查了酸处理多壁碳纳米管对纳米复合材料性能的影响。 TPNR /填料纳米复合材料是通过Thermo Haake内部混合器使用熔融共混法和球磨技术作为预混合方法制备的。酸处理成功地缩短了长度并解开了MWCNT的人群。酸处理的MWCNTs-Fe_3O_4在TPNR基体中的分散性得到改善,酸处理的MWCNTs-Fe_3O_4与TPNR基体之间的界面附着力增强,从而提高了磁性和动态力学性能。酸处理的MWCNTs-Fe_3O_4填充的TPNR与纯TPNR相比,储能模量提高了10%,这是由于MWCNT在TPNR基质中的细分散。

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