Fabrication of silicon oxycarbide foams from extruded blends of polysiloxane, low-density polyethylene (LDPE), and polymer microbead

摘要

Silicon oxycarbide (SiOC) foams with porosities ranging from 77% to 90% and a cell density higher than 108 cells/cm3 were made from polysiloxane, low-density polyethylene (LDPE), and polymer microbead blends. The polysiloxane, LDPE, and polymer microbeads were compounded directly using a counter-rotated twinscrew extruder. The obtained blends were foamed with gaseous carbon dioxide, cross-linked, and subsequently pyrolyzed. The process resulted in the production of highly porous, open-cell SiOC foams with a bimodal distribution of pore morphology, small spherical pores derived from polymer microbeads and relatively large elongated or equiaxed pores derived from foaming using carbon dioxide and decomposition of LDPE.