Hydride Reorientation and Delayed Hydride Cracking of Spent Fuel Rods in Dry Storage

摘要

The aim of this work is to investigate the effect of thermal creep during vacuum drying of spent fuel rods on hydride reorientation and their delayed hydride cracking (DHC) susceptibility. To these ends, we analyzed Tsai’s thermal creep results of irradiated Zircaloy-4 cladding segments from two pressurized water reactors and Simpson and Ells’ observation where zirconium alloy cladding tube failed during long-term storage at room temperature. On cooling under 190 MPa, the spent fuel rods crept to 3.5 pct strain during vacuum drying showed large radial hydrides, while the ones crept to 0.35 pct strain had very fine radial hydrides. Thus, it is suggested that prior creep deformation promotes hydride reorientation in spent fuel rods on cooling after vacuum drying. Evidence for this suggestion is provided by a model experiment. Considering Kim’s DHC model and experimental facts showing precipitation of hydrides even at room temperature at stress raisers, we suggest that spent fuel rods would fail by DHC in dry storage if stress raisers are present inside the cladding on cooling to below 180 °C, and then axial splits of the failed spent fuel rods would occur by DHC due to fuel expansion by UO2 oxidation.