Pre-deposition of iron-based adsorbents on the removal of humic acid using ultrafiltration and membrane fouling

摘要

The effect of three iron-based adsorbents pre-depositing on ultrafiltration membrane for humic acid (HA) removal and membrane fouling was investigated. The result showed that pre-depositing adsorbents on membrane could not only reduce membrane fouling but also enhance HA removal. The flux was related to the adsorbent dosage and the optimal dosage for pre-deposition was 35.0g/m~2. The dissolved organic carbon (DOC) removal of HA was 38.3%, 67.3% and 41.1% respectively when pre-deposited 35.0 g/m~2 FeO_3H_y, MnFe_2O_4 and Fe_3O_4 on membrane. Different adsorption effect of adsorbents on HA contributed to increasing of the flux at different level. Zeta potential of three adsorbents all decreased after adsorbed HA. The adsorption capacity of the three adsorbents was FeO_xH_y > MnFe_2O_4 > Fe_3O_4. Atomic Force Microscopy (AFM) measurement showed the thickness of pre-deposition layers formed by different adsorbents was different. The scanning electron microscope (SEM) detection showed the morphology and compactness of pre-deposition layers formed by different adsorbents was different.