Microstructural investigation of electrochemical hydrogen storage in amorphous Mg-Ni-La alloy

摘要

It has been found that the amorphous Mg_(65)Ni_(27)La_8 alloy prepared by melt-spinning had a maximum discharge capacity of 558 mAh g~(-1). Now, a reversible microstructural transformation of the alloy during electrochemical cycles is detected by X-ray diffraction (XRD) and confirmed using transmission electron microscopy (TEM) and selected area electron diffraction (SAED). Some Mg_2 NiH_4 nanocrystallites appear in the alloy after charging. Most of them are less than 4nm in diameter and metastable. These small nanocrystallites can readily be dehydrogenated and decomposed by discharging. Hydrogen atoms are stored in the amorphous phase and the Mg_2NiH_4 phases. The amorphous phase can absorb and desorb H atoms effectively and efficiently, and facilitate the dehydrogenation of these small Mg_2NiH_4 nanocrystallites. The high discharge capacity is attributed to a synergistic effect of the small nanocrystallites of Mg_2Ni hydrides and the amorphous phase around them.