Study on the microstructure and electrochemical kinetic properties of MmNi_(4.50-χ)Mn_χCo_(0.45)Al_(0.30) (0.25 ≤ χ ≤ 0.45) hydrogen storage alloys

摘要

The phase structures, surface morphologies and electrochemical kinetic properties of MmNi_(4.50-χ)Mn_χCo_(0.45)Al_(0.30) (Mm is the mischmetal, χ = 0.25, 0.30, 0.35, 0.40 and 0.45) hydrogen storage alloys have been investigated in this paper. The X-ray diffraction (XRD) shows that all the alloys mainly consist of LaNi_5 phase with CaCu_5-type structure, which belongs to P6/mmm space group (central symmetry). Scanning electron microscopy (SEM) tests indicate that there are partial element segregations in the alloys. Meanwhile, energy dispersive spectrum (EDS) results display that the elements constituting Mm exist in the matrix phase in relatively larger proportion, while Mn, AI and Co tend to appear in precipitate phase. For the alloy with χ=0.35, the electrochemical performances, including discharge capacity, high-rate dischargeability (HRD) and cycling life, of the alloy electrode are better than that of other alloy electrodes. With the increase of Mn content, the exchange current density (I_0) of the alloy electrodes first increases and then decreases, the hydrogen diffusion coefficient (D) of alloy electrodes gradually decreases. There is a linear correlation between HRD at a discharge current density of 1500 mA/g and I_0.