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Magnetic composite nanofibers fabricated by electrospinning of Fe_3O_4/gelatin aqueous solutions

机译:Fe_3O_4 /明胶水溶液电纺丝制备的磁性复合纳米纤维

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摘要

We have fabricated magnetic composite nanofibers containing superparamagnetic Fe_3O_4 nanoparti-cles by the electrospinning method. Highly dispersed Fe_3O_4 magnetic nanoparticles were synthesized by one-step co-precipitation of Fe~(2+)/Fe~(3+) under an alkaline condition with 4wt% poly(vinyl alcohol) (PVA) aqueous solution as the stabilizer. Gelatin (GE) was used as a polymeric matrix for fabricating the nanocomposites. The prepared Fe_3O_4/GE composite nanofibers were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD), respectively. These composite nanofibers show uniform and continuous morphology with the Fe_3O_4 nanoparticles embedded in the nanofibers. By studying the magnetic properties of the Fe_3O_4/GE composite nanofibers, we confirm that the composite nanofibers possess superparamagnetic properties with a high saturated magnetization (M_s= 12.87emμ g~(-1)) at room temperature. The features of this approach for getting one-dimensional magnetic nanostructure are its simplicity, effectiveness and safety. The Fe_3O_4/GE nanofibers with superparamagnetic properties would be potentially applied in biomedical field.
机译:我们通过电纺丝法制备了包含超顺磁性Fe_3O_4纳米粒子的磁性复合纳米纤维。在碱性条件下,以4%(重量)聚乙烯醇(PVA)水溶液为稳定剂,一步一步沉淀Fe〜(2 +)/ Fe〜(3+),合成了高度分散的Fe_3O_4磁性纳米粒子。明胶(GE)被用作制造纳米复合材料的聚合物基质。分别用扫描电子显微镜(SEM),透射电子显微镜(TEM)和X射线衍射(XRD)对制备的Fe_3O_4 / GE复合纳米纤维进行表征。这些复合纳米纤维表现出均匀且连续的形态,其中Fe_3O_4纳米粒子嵌入纳米纤维中。通过研究Fe_3O_4 / GE复合纳米纤维的磁性能,可以确定该复合纳米纤维在室温下具有超饱和饱和磁化强度(M_s =12.87emμg〜(-1))的超顺磁性。这种获得一维磁性纳米结构的方法的特点是它的简单性,有效性和安全性。具有超顺磁性的Fe_3O_4 / GE纳米纤维将有可能应用于生物医学领域。

著录项

  • 来源
    《Materials Science and Engineering》 |2014年第12期|126-132|共7页
  • 作者单位

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    Key Laboratory of Functional Inorganic Material Chemistry (School of Chemical Engineering and Material, Heilongjiang University), Ministry of Education, Harbin 150080, PR China;

    College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, PR China;

    College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Nanocomposites; Magnetic materials; Electrospinning; Fe_3O_4 nanoparticle;

    机译:纳米复合材料;磁性材料;电纺;Fe_3O_4纳米粒子;

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