Spark-plasma-sintering (SPS) of nanostructured and submicron titanium oxide powders

摘要

Spark-plasma-sintering (SPS) consolidation of submicron and nanostructured titanium oxide (TiO_2) powders was performed between 800 and 1000℃ for 1 min. The results were compared with conventional sintering using electrical resistant furnace that was performed between 600 and 1000℃ for 120 min. The compacted samples were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). This investigation clearly shows that the SPS method is capable of obtaining samples with high densities and corresponding fine grain-size from nanostructured raw TiO_2 powder. Remarkable difference in the sintering techniques was observed in samples with >95% theoretical density where the relative grain growth quotient d/d_o for the 40 nm powder was ～ 3 when SPS was employed while the value obtained for conventional sintering was ～ 26.