Structure and electrochemical performance of nickel hydroxide synthesized by rapid quench method

摘要

Nickel hydroxide with amorphous structure has been synthesized successfully by chemical precipitation method combined with rapid quench technique. The microstructure and morphology of the prepared samples were analyzed by XRD, Raman spectra, IR spectra, and SEM. The electrochemical performance of the sample was characterized by cyclic voltammetry, electrochemical impedance spectroscopy, and charge/discharge tests. The discharge capacity of the amorphous nickel hydroxide is 330.0 mAh g~(-1) at 0.2C, much higher than that of the theoretical capacity of β-nickel hydroxide (289.0 mAh g~(-1)). Moreover, the amorphous nickel hydroxide exhibits higher electrochemical reaction reversibility, lower electrochemical impedance, and better cyclic stability compared with β-nickel hydroxide.