Low-temperature formation of alpha alumina powders from carboxylate and mixed carboxylate precursors

摘要

Formation of alpha alumina fine powders from aluminum carboxylate and mixed carboxylate precursors have been studied using thermoanalytical and powder X-ray diffraction techniques. Among these carboxylates, aluminum acetate and formoacetate produce alpha alumna below 100degC, whereas, the other precursors require about 1200degC. The nature of the precursor has been found to influence the course of thermal decomposition and the sequence of phase evolution. The resultant alpha alumna powders have been have been characterized employing surface area and porosity measurements.