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Low temperature preparation and characterization of CdTiO_3 nanoplates

机译:CdTiO_3纳米板的低温制备与表征

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摘要

An alternative low cost method was proposed for the Sow temperature (600 ℃) preparation of CdTiO_3 nanoplates, using low-melting-point Cd(NO_3)_2·4H_2O and high-reactive-activity TiO_2 nanocrystals as the reactants. The structure, composition, specific surface area, thermal stability and optical properties of the as-synthesized products were characterized by X-ray diffraction, energy dispersive X-ray spectroscopy, field emission scanning electron microscopy, Brunauer-Emmett-Teller surface area analysis, UV-vis absorption and room temperature photoluminescence spectra. The as-synthesized CdTiO_3 nanoplates were thermally stable at temperatures <900 ℃, and their phase changed from ilmenite to perovskite when heated in air at 1000 ℃ for 2 h. Besides, they exhibited a strong and broad visible light emission in the range of about 470-750 nm upon laser excitation at 325 nm, enabling their use as a luminescent material.
机译:提出了一种以低熔点Cd(NO_3)_2·4H_2O和高反应活性TiO_2纳米晶为反应物,在600℃低温制备CdTiO_3纳米板的方法。通过X射线衍射,能量色散X射线光谱,场发射扫描电子显微镜,Brunauer-Emmett-Teller表面积分析等方法表征了合成产物的结构,组成,比表面积,热稳定性和光学性质。紫外可见吸收和室温光致发光光谱。合成后的CdTiO_3纳米板在<900℃的温度下具有热稳定性,并且在空气中于1000℃加热2 h后其相从钛铁矿变为钙钛矿。此外,当在325 nm处进行激光激发时,它们在约470-750 nm的范围内显示出强而宽的可见光发射,从而使其可用作发光材料。

著录项

  • 来源
    《Materials Letters》 |2011年第18期|p.2601-2603|共3页
  • 作者单位

    Department of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453000, China;

    Department of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453000, China;

    School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;

    School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;

    School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    ceramics; semiconductors; nanocrystalline materials; luminescence;

    机译:陶瓷;半导体;纳米晶体材料;发光;

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