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A true nanocomposite: Single crystalline Au nanoparticles on single crystalline Fe_3O_4 nanoparticles

机译:真正的纳米复合材料:单晶Fe_3O_4纳米颗粒上的单晶Au纳米颗粒

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摘要

An Au/Fe_3O_4 nanocomposite catalyst was fabricated through a simple deposition-precipitation method. The Au/Fe_3O_4 nanocomposite is a true nanocomposite that has single crystalline Au nanoparticles supported on single crystalline Fe_3O_4 nanoparticles. Lattice fringes from both Au and Fe_3O_4 single nanoparticles were simultaneously observed by transmission electron microscope (TEM). This nanocomposite catalyst showed much high activity in low temperature CO oxidation reaction. The Au/Fe_3O_4 nanocomposite catalyst reaches 100% CO conversion at 40 ℃. In comparison, Au/commercial Fe_3O_4 catalyst needs 375 ℃ to convert CO. This Au/Fe_3O_4 nanocomposite is an ideal sample to study synergetic effect between the catalyst and the support at nanoscale.
机译:通过简单的沉积沉淀法制备了Au / Fe_3O_4纳米复合催化剂。 Au / Fe_3O_4纳米复合材料是一种真正的纳米复合材料,具有负载在单晶Fe_3O_4纳米颗粒上的单晶Au纳米颗粒。通过透射电子显微镜(TEM)同时观察到来自Au和Fe_3O_4单个纳米颗粒的晶格条纹。该纳米复合催化剂在低温CO氧化反应中显示出很高的活性。 Au / Fe_3O_4纳米复合催化剂在40℃时达到100%CO转化率。相比之下,Au /商业Fe_3O_4催化剂需要375℃才能转化CO。这种Au / Fe_3O_4纳米复合材料是研究催化剂与载体在纳米尺度上协同作用的理想样品。

著录项

  • 来源
    《Materials Letters》 |2011年第1期|p.82-84|共3页
  • 作者单位

    School of Chemistry and Environment, Beihang University, Beijing, 100191, PR China;

    National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;

    National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;

    National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;

    School of Chemistry and Environment, Beihang University, Beijing, 100191, PR China,National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    nanocomposites; nanocrystalline materials; crystal structure; CO oxidation; Fe_3O_4 nanoparticles;

    机译:纳米复合材料纳米晶体材料;晶体结构一氧化碳Fe_3O_4纳米粒子;

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