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Facile synthesis of novel SWCNT/HgS nanohybrid: An effective photocatalyst for degradation of methylene blue

机译:新型SWCNT / HgS纳米杂合物的简便合成:一种有效的亚甲基蓝降解光催化剂

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Mercury sulphide (HgS) nanoparticles decorated single walled carbon nanotubes (SWCNT/HgS) were synthesized via a hydrothermal route. We investigated structural and photocatalytic properties of SWCNT/HgS nanohybrid. The diameter of pure SWCNTs and SWCNT/HgS as determined by Raman spectroscopy was 1.607 nm and 1.646 nm, respectively. Hexagonal phase of alpha-HgS nanoparticles decorated on SWCNTs was evidenced in HRTEM, SAED, XPS and XRD spectra. An increase in photocatalytic efficiency of SWCNT/HgS nanohybrid (99.08%) as compared to HgS NPs (73.0%) was observed for photodegradation of methylene blue (5 ppm) under sunlight. This study suggests a promising approach to rational design of advanced heterogeneous photocatalysts for environmental remediation. (C) 2019 Elsevier B.V. All rights reserved.
机译:通过水热法合成了装饰有单壁碳纳米管(SWCNT / HgS)的硫化汞(HgS)纳米颗粒。我们研究了SWCNT / HgS纳米杂化物的结构和光催化性能。通过拉曼光谱法测定的纯SWCNT和SWCNT / HgS的直径分别为1.607nm和1.646nm。在HRTEM,SAED,XPS和XRD光谱中证实了在SWCNT上装饰的α-HgS纳米颗粒的六方相。对于亚甲基蓝(5 ppm)在阳光下的光降解,观察到SWCNT / HgS纳米杂化物的光催化效率(99.08%)比HgS NPs(73.0%)的增加。这项研究提出了一种有前途的方法,可以合理设计用于环境修复的高级多相光催化剂。 (C)2019 Elsevier B.V.保留所有权利。

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