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Mechanical properties of high density polyethylene reinforced with chemically modified coir fibers: Impact of chemical treatments

机译:化学改性椰壳纤维增强的高密度聚乙烯的机械性能:化学处理的影响

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摘要

In this work, high density polyethylene (HDPE) was compounded with chemically treated coir fiber using a heated two roll mill. Three chemical treatments denoted silane, sodium hydroxide (NaOH) and dode-cane bromide (C12) were selected to improve the interface adhesion between fibers and polyethylene matrix. The mechanical properties of these composites were evaluated and compared against those of neat polymer and untreated fibers composites. A fixed fiber loading of 20 wt.% was used in all composites. A chemical analysis using Fourier Transform Infrared spectroscopy (FTIR) was performed to see the extent of chemical modification of the fibers. Results have shown that tensile and torsional modulus exhibited a significant increase when compared to the neat HDPE. A notable increase in the Young's modulus was observed when C12 and silane were used, corresponding to 120% and 70%, respectively. The composites' ductility was also evaluated by the plastic stored energy and showed a noted increase when C12 and silane were used, an increase of 55% with C12 treatment and 23% when silane treatment was used. Such results promise many applications for composite materials.
机译:在这项工作中,使用加热的两辊磨将高密度聚乙烯(HDPE)与经过化学处理的椰壳纤维复合。选择了三种化学处理方法,分别表示硅烷,氢氧化钠(NaOH)和十二烷基溴化物(C12),以改善纤维与聚乙烯基体之间的界面粘合力。对这些复合材料的机械性能进行了评估,并将其与纯聚合物和未处理的纤维复合材料的机械性能进行了比较。在所有复合物中均使用20 wt。%的固定纤维负载量。使用傅里叶变换红外光谱仪(FTIR)进行了化学分析,以查看纤维的化学修饰程度。结果表明,与纯HDPE相比,拉伸模量和扭转模量显示出显着增加。当使用C12和硅烷时,观察到杨氏模量的显着增加,分别对应于120%和70%。还通过塑料的储能来评估复合材料的延展性,当使用C12和硅烷时,复合材料的延展性显着提高;使用C12处理时,复合材料的延展性提高了55%,使用硅烷处理时,复合材料的延展性提高了23%。这样的结果有望用于复合材料的许多应用。

著录项

  • 来源
    《Materials & design》 |2012年第5期|p.379-383|共5页
  • 作者单位

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco,Faculty of Science, Mohammed V University, Rabat, Morocco;

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco,Faculty of Science, Mohammed V University, Rabat, Morocco;

    Laval University, Department of Chemical Engineering, Ste-Foy, Quebec, Canada CIK 7P4;

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco;

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco;

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco;

    Hassan II Academy of Science and Technology, Rabat, Morocco;

    Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Institute of Nanomaterials and Nanotechnology, Morocco;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    A. polymer matrix; E. mechanical; F. chemical-reaction;

    机译:A.聚合物基质;E.机械;F.化学反应;

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