Recyclable liquid-like POSS derivatives with designed structures and their potential for CO2 capture

摘要

Six kinds of liquid-like trisilanol isobutyl-POSS derivatives are designed and synthesized to study the influences of their structures on capturing CO2. The derivatives are different in bonding types, -NH content, flow ability, grafting ratio or molecular size. The CO2 capture property of these derivatives is tested. It is found that bonding types can affect the recycle property, -NH content can affect the chemical absorption, molecular size can affect the physical adsorption, and flow ability can affect both chemical absorption and physical adsorption. Furthermore, the physical adsorption is determining factor that cause differences from liquid-like derivatives to traditional amine based solvents CO2 absorbents. (C) 2016 Elsevier Ltd. All rights reserved.