Congener-specific distribution and bioaccumulation of short-chain chlorinated paraffins in sediments and bivalves of the Bohai Sea, China

摘要

Short-chain chlorinated paraffins (SCCPs) are a new type of persistent organic pollutants that are of great environmental concern because of their wide distribution. In this study, surface sediments and bivalve samples were collected from the coastal area of the Bohai Sea in China. Total SCCP (XSCCP) concentrations in surface sediments and bivalves ranged from 97.4 ng g~(-1) dry weight (dw) to 1756.7 ng g~(-1) dw and 476.4-3269.5 ng g~(-1) dw, respectively. C_(10)-CPs and C_(11)-CPs were the predominant homologue groups in all sediments and bivalves. Specific congener composition analysis and correspondence analysis indicated that the local SCCP source mainly came from CP-42 and CP-52 products, and riverine input had an important function. The biota-sediment accumulation factors of ΣSCCPs for bivalves ranged from 1.08 to 1.61, and a significant correlation indicated that the SCCP congener with higher chlorination degree was more likely to be accumulated in bivalves.