Visible–Near Infrared Point Spectrometry of Drill Core Samples from Río Tinto, Spain: Results from the 2005 Mars Astrobiology Research and Technology Experiment (MARTE) Drilling Exercise

摘要

Sampling of subsurface rock may be required to detect evidence of past biological activity on Mars. The MarsnAstrobiology Research and Technology Experiment (MARTE) utilized the Río Tinto region, Spain, as a Marsnanalog site to test dry drilling technologies specific to Mars that retrieve subsurface rock for biological analysis.nThis work examines the usefulness of visible–near infrared (VNIR) (450–1000 nm) point spectrometry toncharacterize ferric iron minerals in core material retrieved during a simulated Mars drilling mission. VNIR spectrometryncan indicate the presence of aqueously precipitated ferric iron minerals and, thus, determine whethernbiological analysis of retrieved rock is warranted. Core spectra obtained during the mission with T1 (893–897nnm) and T2 (644–652 nm) features indicate goethite-dominated samples, while relatively lower wavelength T1n(832–880 nm) features indicate hematite. Hematite/goethite molar ratios varied from 0 to 1.4, and within then880–898 nm range, T1 features were used to estimate hematite/goethite molar ratios. Post-mission X-ray analysisndetected phyllosilicates, which indicates that examining beyond the VNIR (e.g., shortwave infrared,n1000–2500 nm) will enhance the detection of other minerals formed by aqueous processes. Despite the limitednspectral range of VNIR point spectrometry utilized in the MARTE Mars drilling simulation project, ferric ironnminerals could be identified in retrieved core material, and their distribution served to direct core subsamplingnfor biological analysis.