The physical solubilities and diffusivities of N_2O and CO_2 in aqueous ammonia solutions on the additions of AMP, glycerol and ethylene glycol

摘要

Carbon dioxide (CO_2) is a major greenhouse gas, the emissions of which should be reduced. There are various technologies for the effective separation of CO_2. Of these, chemical absorption methods are generally accepted as the most effective. The monoethanolamine (MEA) process is an effective way to remove CO_2, but is an expensive option for the separation of CO_2 from massive gas-discharging plants. Therefore, ammonia solution, which is less expensive and more effective than MEA, was used for the removal of CO_2. In this study, the physical solubility of N_2O in (ammonia+water), (ammonia+2-arnino-2-methyl-l-propanol+water), (ammonia+glycerol+water) and (ammonia+ ethylene glycol+water) was measured at 293,303,313, 323 K. Additive concentrations of 1,3, and 5 wt% AMP, glycerol and ethylene glycol were added for each 9 wt% ammonia solution. A solubility apparatus was used to investigate the solubility of N_2O in ammonia solutions. The diffusivity was measured with a wetted wall column absorber. The "N_2O analogy" is used to estimate the solubility and diffusivity of CO_2 in the aqueous ammonia solutions. OriginPro 7.5 was used to correlate the solubility and diffusivity of N_2O in ammonia solutions. The parameters of the correlation were determined from the measured solubility and diffusivity.