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Room-temperature synthesis of Co_3O_4 nanoparticles self-assembled into mesoanoporous microstructures and their application

机译:自组装成介孔/纳米孔微结构的Co_3O_4纳米粒子的室温合成及其应用

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摘要

Nano/mesoporous transition metal oxides have attracted extensive attention because of their distinctive morphology and properties, along with exhibiting better performance in many applications. We employed a simple modified version of the one-pot co-precipitation method at room temperature to synthesize three-dimensional mesoporous microstructures obtained by the self-aggregation of Co3O4 nanoparticles, which is sparse in the literature. The obtained structures were used as electrode materials for electrochemical capacitors or supercapacitors. The as-obtained Co3O4 electrode exhibited acceptable specific capacitances of 400 and 165 F center dot g(-1) at applied current densities of 1 and 10 A center dot g(-1), respectively, with over 99% of capacity retention after 4000 cycles.
机译:纳米/介孔过渡金属氧化物因其独特的形态和性能以及在许多应用中表现出的优异性能而受到广泛关注。我们在室温下采用一锅共沉淀法的简单修改版来合成通过Co3O4纳米粒子的自聚集获得的三维介孔微观结构,这在文献中是稀疏的。所获得的结构用作电化学电容器或超级电容器的电极材料。所获得的Co3O4电极在施加的电流密度分别为1和10 A中心点g(-1)时分别表现出400和165 F中心点g(-1)的可接受的比电容,4000后的容量保持率超过99%周期。

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