Zn(tbip) (H_2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability

摘要

Recent studies have uncovered numerous interesting and promising gas sorption properties of microporous metal organic frameworks (MMOFs),including gas separation and hydrogen sorption.However,for any practical applications,it is very important that these MMOF materials are structurally robust and thermally stable.Unfortunately,thermal instability is a major problem for many of the MMOFs.