Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (W0R4) from Pyrococcus furiosus

Hideki Sugimoto; Hiroyuki Tano; Kazuo Toyota; Reiko Tajima; Hiroyuki Miyake; Isao Takahashi; Shun Hirota; Shinobu Itoh

首页> 外文期刊>Journal of the American Chemical Society >Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (W0R4) from Pyrococcus furiosus

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Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (W0R4) from Pyrococcus furiosus

机译：与双氢还原双（二硫代亚乙基）氧代（二硫代）钨（VI）配合物与激烈火球菌中第四种含钨酶（W0R4）的化学功能相关

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Discovery of the fourth tungsten oxidoreductase (WOR4) from hyperthermophilic archaeon Pyrococcus furiosus has expanded coordination and bioinorganic chemistry of heavy metal ions. The WOR4 enzyme plays an important role in the elemental sulfur (S~0) metabolism, reducing S~0 to hydrogensulfide in the presence of dihydrogen (eq 1). By this function, the WOR4 enzyme is distinguished from other tungsten enzymes.

机译：从嗜热古细菌激烈热球菌中发现第四种钨氧化还原酶（WOR4），扩大了重金属离子的配位和生物无机化学。 WOR4酶在元素硫（S〜0）代谢中起重要作用，在存在二氢（eq 1）的情况下将S〜0还原为硫化氢。通过此功能，WOR4酶不同于其他钨酶。

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来源
《Journal of the American Chemical Society》 |2010年第1期|8-9|共2页
作者
Hideki Sugimoto; Hiroyuki Tano; Kazuo Toyota; Reiko Tajima; Hiroyuki Miyake; Isao Takahashi; Shun Hirota; Shinobu Itoh;
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作者单位

Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan;

Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara 630-0192, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 03:15:24

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1. Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (WOR4) from Pyrococcus furiosus [J] . Hideki Sugimoto Hiroyuki Tano Kazuo Toyota Reiko Tajima Hiroyuki Miyake Isao Takahashi Shun Hirota and Shinobu Itoh Journal of the American Chemical Society . 2010,第1期

机译：与双氢还原双（二硫代亚乙基）氧代（二硫代）钨（VI）配合物与激烈火球菌中的第四种含钨酶（WOR4）的化学功能相关
2. Characterization of a Fourth Tungsten-Containing Enzyme from the Hyperthermophilic Archaeon Pyrococcus furiosus [J] . Roopali Roy, Michael W. W. Adams Journal of bacteriology . 2002,第24期

机译：嗜热古细菌火球菌中第四种含钨酶的表征
3. In Situ Generation of Oxo-sulfidobis(dithiolene)tungsten(VI) Complexes:Active-Site Models for the Aldehyde Ferredoxin Oxidoreductase Family of Tungsten Enzymes [J] . Hideki Sugimoto, Hiroyuki Tano, Reiko Tajima Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第21期

机译：氧合硫双（二硫代）钨（VI）配合物的原位生成：钨酶醛铁氧还蛋白氧化还原酶家族的活性位点模型
4. SYNTHESIS AND CATION COMPLEXATION INDUCED ELECTROCHEMICAL BEHAVIOR OF BIS-FUNCTIONALIZED FULLERENE-DIBENZO-18-CROWN-6 CONJUGATES [C] . Francis DSouza, Amy L. McCarty, Phillip M. Smith Electrochemical Society Annual Meeting . 2005

机译：合成和阳离子络合诱导双官能化富勒烯-dibenzo-18的电化学行为18 -c-6缀合物
5. Characterization of a Fourth Tungsten-Containing Enzyme from the Hyperthermophilic Archaeon Pyrococcus furiosus [O] . Roopali Roy, Michael W. W. Adams 2002

机译：嗜热古细菌火球菌中第四种含钨酶的表征
6. Characterization of a Fourth Tungsten-Containing Enzyme from the Hyperthermophilic Archaeon Pyrococcus furiosus [O] . Roy, Roopali, Adams, Michael W. W. 2002

机译：嗜热古细菌火球菌中第四种含钨酶的表征
7. Kinetic Study of the Formation of the Oxo Diperoxo Complexes of Molybdenum(VI) and Tungsten(VI) and their Reduction by Iron(II), Europium(II), the Methyl Viologen Radical Cation, and the Dithionite Ion. [R] . 1989

机译：钼（VI）和钨（VI）的氧代二过氧配合物的形成和铁（II），铕（II），甲基紫精阳离子和连二亚离子的还原的动力学研究。

Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (W0R4) from Pyrococcus furiosus

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