Mimicking Zeolite to Its Core: Porous Socialite Cages as Hangers for Pendant Trimeric M_3(OH) Clusters (M = Mg, Mn, Co, Ni, Cd)

摘要

A new class of zeolite-type porous materials in which 3D frameworks are covalently functionalized with crystallographically ordered pendant metal clusters have been synthesized. This work demonstrates a new paradigm for and the feasibility of functionalizing zeolite-type frameworks through the conversion of extraframework sites in mineral zeolites into part of the framework for occupation by dangling metal clusters in metal-organic frameworks.