A Switchable [2]Rotaxane Asymmetric Organocatalyst That Utilizes an Acyclic Chiral Secondary Amine

Victor Blanco; David A. Leigh; Vanesa Marcos; Jose A. Morales-Serna; Alina L. Nussbaumer

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A Switchable [2]Rotaxane Asymmetric Organocatalyst That Utilizes an Acyclic Chiral Secondary Amine

机译：利用无环手性仲胺的可切换[2]轮烷不对称有机催化剂

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A rotaxane-based switchable asymmetric organocatalyst has been synthesized in which the change of the position of the macrocyde reveals or conceals an acyclic, yet still highly effective, chiral organocatalytic group. This allows control over both the rate and stereochemical outcome of a catalyzed asymmetric Michael addition.

机译：已经合成了基于轮烷的可转换不对称有机催化剂，其中大环化合物位置的变化揭示或掩盖了无环但仍然非常有效的手性有机催化基团。这允许控制催化的不对称迈克尔加成的速率和立体化学结果。

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来源
《Journal of the American Chemical Society》 |2014年第13期|4905-4908|共4页
作者
Victor Blanco; David A. Leigh; Vanesa Marcos; Jose A. Morales-Serna; Alina L. Nussbaumer;
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作者单位

School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom;

School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom;

School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom;

School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom;

School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
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入库时间 2022-08-18 03:11:08

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1. Acyclic Amino Acid Based Bifunctional Chiral Tertiary Amines, Quaternary Ammoniums and Iminophosphoranes as Organocatalysts [J] . Zhao Xiaowei, Zhu Bo, Jiang Zhiyong Synlett . 2015,第16期

机译：基于无环氨基酸的双功能手性叔胺，季铵盐和亚氨基正膦作为有机催化剂
2. Enantioselectivity Switch in Direct Asymmetric Aminoxylation Catalyzed by Binaphthyl-Based Chiral Secondary Amines [J] . Taichi Kano, Akihiro Yamamoto, Fumitaka Shirozu, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2009,第9期

机译：基于联萘基的手性仲胺催化直接不对称氨氧化中的对映选择性转换
3. Complete Switch Of Product Selectivity In Asymmetric Direct Aldol Reaction With Two Different Chiral Organocatalysts From A Common Chiral Source [J] . Keiji Nakayama, Keiji Maruoka Journal of the American Chemical Society . 2008,第52期

机译：完全手性来源与两种不同的手性有机催化剂在不对称直接羟醛反应中产物选择性的完全转换
4. A Crystal Structure of the R-Amine Transaminase from Arthrobacter for Asymmetric Catalysis of Chiral Amines [C] . Lijun Guan, Nina Ji, Qinghong Meng, . 2018

机译：节杆菌的R-胺转氨酶的晶体结构用于手性胺的不对称催化
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Investigations Concerning the Syntheses of TADDOL-Derived Secondary Amines and Their Use To Access Novel Chiral Organocatalysts [O] . Katharina Gratzer, Mario Waser -1

机译：关于Taddol衍生的中胺合成及其用于进入新型手性有机催化剂的研究
7. A switchable [2]rotaxane asymmetric organocatalyst that utilizes an acyclic chiral secondary amine [O] . Blanco, Victor, Leigh, David A., Marcos, Vanesa, 2014

机译：可转换的[2]轮烷不对称有机催化剂，其使用非环状手性仲胺

A Switchable [2]Rotaxane Asymmetric Organocatalyst That Utilizes an Acyclic Chiral Secondary Amine

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