• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of the American Chemical Society >Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature
【24h】

Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature

机译：胍基-甲ami鎓碘化铅：与钙钛矿相关的层状化合物，在室温下具有红色发光

获取原文
获取原文并翻译 | 示例
       
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two-dimensional hybrid organic–inorganic lead halides perovskite-type compounds have attracted immense scientific interest due to their remarkable optoelectronic properties and tailorable crystal structures. In this work, we present a new layered hybrid lead halide, namely [CH(NH_(2))_(2)][C(NH_(2))_(3)]PbI_(4), wherein puckered lead-iodide layers are separated by two small and stable organic cations: formamidinium, CH(NH_(2))_(2)~(+), and guanidinium, C(NH_(2))_(3)~(+). This perovskite is thermally stable up to 255 °C, exhibits room-temperature photoluminescence in the red region with a quantum yield of 3.5%, and is photoconductive. This study highlights a vast structural diversity that exists in the compositional space typically used in perovskite photovoltaics.
机译：二维杂化有机-无机卤化铅钙钛矿型化合物因其卓越的光电性能和可定制的晶体结构而引起了巨大的科学兴趣。在这项工作中，我们提出了一种新的层状混合卤化铅，即[CH（NH_（2））_（2）] [C（NH_（2））_（3）] PbI_（4），其中起皱的碘化铅层被两个小的稳定的有机阳离子隔开：甲ami CH（NH_（2））_（2）〜（+）和胍鎓C（NH_（2））_（3）〜（+）。该钙钛矿在高达255°C的温度下具有热稳定性，在红色区域显示室温光致发光，量子产率为3.5％，并且具有光电导性。这项研究强调了钙钛矿光伏电池通常使用的成分空间中存在的巨大结构多样性。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2018年第11期|3850-3853|共4页
  • 作者

    Olga Nazarenko; Martin R. Kotyrba; Sergii Yakunin; Marcel Aebli; Gabriele Rainò; Bogdan M. Benin; Michael Wörle; Maksym V. Kovalenko;

  • 作者单位

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland;

    Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, Vladimir Prelog Weg 1, CH-8093 Zürich, Switzerland,Laboratory for Thin Films and Photovoltaics, Empa − Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-18 03:07:19

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号