Unexpected reaction of 2-chloro-1-propen-3-yl isothiuronium chloride with potassium ditelluride: the first example of vicinal elimination of chlorine and sulfur-bearing moieties

摘要

2-Chloro-1-propen-3-yl isothiuronium chloride reacts with potassium ditelluride in hydrazine hydrate to afford elemental tellurium and allene. The latter is formed due to the vicinal elimination of chlorine and a sulfur-bearing moiety.View full textDownload full textKeywordsisothiuronium salt, elimination, allene, hydrazine hydrate, telluriumRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/17415993.2012.710909