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Supported Perovskites as Catalysts for CO Oxidation

机译:支持的钙钛矿作为CO氧化的催化剂

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Lanthanum and barium ferrites as wll as lanthanum cobaltate binary oxidic species supported on alumina and zirconia were tested for their catalytic activity for the CO oxidation reactions. Synthesized perovskite oxides were supported on alumina or zirconia by dry impregnation. For the same percent loading of the perovskite (5.8 per cent), LaCoO_3/ZrO_2 were found to be most active in comparison of Las-Co-O solids supported don ziroconia may be attributed to better reactivity of Co at B-site in comparison to F, homogeneous and higher dispersion on zirconia in comparison to alumina, ionic oxygen carrying Capacity of zirconia and larger ionic size of Zr~4+ Ion.
机译:测试了负载在氧化铝和氧化锆上的镧和钡铁氧体(如钴酸镧二元氧化物)对CO氧化反应的催化活性。通过干浸渍将合成的钙钛矿氧化物负载在氧化铝或氧化锆上。对于相同百分比的钙钛矿(5.8%),发现LaCoO_3 / ZrO_2与Las-Co-O固体负载的氧化锆相比具有最高的活性,这可能归因于Co在B位置的反应性优于F,与氧化铝相比,在氧化锆上均匀且分散性高,氧化锆的离子携氧能力和更大的Zr〜4 +离子尺寸。

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