Structure of the secondary phase and its effects on hydrogen-storage properties in a Ti_(0.7)Zr_(0.2)V_(0.1)Ni alloy

摘要

The phase structures and hydrogen storage properties of a Ti_(0.7)Zr_(0.2)V_(0.1) Ni alloy are studied. It is found that this alloy consists of a matrix and a secondary phase. The matrix is a B2-type compound with bcc structure and the secondary phase is a C14-type Laves phase with hexagonal structure. This alloy electrode has a larger charge-discharge capacity than stoichiometric TiNi electrodes but shows poorer activation behaviour. Optimizing the content of secondary phase is necessary for improving the overall hydrogen-storage properties of substituted Ti-Ni system alloys.