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Microvolammetry for cathode materials at elevated temperatures: electrochemical stability of single particles

机译:阴极材料在高温下的微体积分析:单个颗粒的电化学稳定性

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摘要

The electrochemical stability of single particles of cathode materials (LiMn_2O_4, Li_1.10Cr_0.048Mn_1.852O_4, LiCoO_2 an LiNi_0.85Co_0.15O_2) was investigated by means of a microelecctrode technique at 25deg.c and 50deg.c. The cycle stability was evaluated by multi-cyclic voltammetry. LiMn_2O_4 showed good cycle stability in LiCIO_4/propylene carbonate (PC)+ethylene carbonate (EC) and LiBF_4/PC+EC solutions even at 50deg.c.
机译:通过微电极技术在25℃和50℃下研究了正极材料(LiMn_2O_4,Li_1.10Cr_0.048Mn_1.852O_4,LiCoO_2和LiNi_0.85Co_0.15O_2)的单颗粒的电化学稳定性。通过多循环伏安法评估循环稳定性。 LiMn_2O_4在LiCIO_4 /碳酸亚丙酯(PC)+碳酸亚乙酯(EC)和LiBF_4 / PC + EC溶液中也显示出良好的循环稳定性,即使在50°C时也是如此。

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