Silver-silver sulfate reference electrodes for use in lead-acid batteries

摘要

Electrochemical properties of silver-silver sulfate reference electrodes for lead-acid batteries are described, and the following possible applications discussed: 1. Determination of individual capacities of positive and negative plates. 2. Monitoring individual electrode behavior during deep discharge and cell reversal. 3. Optimization charge or discharge parameters, by controlling the current such that pre-determined limits of positive or negative half-cell potential are respected. 4. Observation of acid concentration differences, for example due to acid stratification, by measuring diffusion potentials (concentration-cell voltages). 5. Detection of defective cells, and defective plate sets, in a string of cells, at the end of their service life. Silver-silver sulfate reference electrodes, permanently installed in lead-acid cells, may be a means to improve battery management, and therewith to improve reliability and service life. In vented batteries, reference electrodes may be used to limit positive plate polarization during charge, or float-charge. Limiting the positive half-cell potential to an upper, pre-set value would permit to keep anodic corrosion as low as possible. During cycling, discharge could be terminated when the half-cell potential of the positive electrode has dropped to a pre-set limit. This would prevent excessive discharge of the positive electrodes, which could result in an improvement of cycle life. In valve-regulated batteries, reference electrodes may be used to adjust float-charge conditions such as to assure sufficient cathodic polarization of the negative electrodes, in order to avoid sulfation. The use of such reference electrodes could be beneficial particularly in multi-cell batteries, with overall voltages above 12 V, operated in a partial-state-of-charge.