Comparison of the surface changes on cathode during long term storage testing of high energy density cylindrical lithium-ion cells

摘要

Nickel-based oxide cathode material taking out from lithium-ion cell after storage for 2 years at 45 C is analyzed by electron energy-loss spectroscopy in a scanning transmission electron microscope (STEM-EELS) and the result of STEM-EELS is compared with cobalt-based oxide cathode material which is treated as same manor as nickel-based oxide cathode material. The Ni-L2,3 energy-loss near-edge structure (ELNES) spectra of nickel-based oxide cathode material show peak positions similar to original material before storage. This result indicates that nickel-based oxide material has no significant change in the surface structure. On the other hand, a remarkable shift to low energy is observed in the C0-L2.3 ELNES spectra of the cobalt-based oxide cathode material after storage. The cycle test at 60 C under the conditions of aggressive driving cycle (US06) mode for the nickel-based oxide cathode/graphite cell is also carried out. It is clear that cycle performance of the nickel-based oxide cathode/graphite cell is dependent on the depth of discharge (DOD).