Development of Ni-Ba(Zr,Y)O-3 cermet anodes for direct ammonia-fueled solid oxide fuel cells

摘要

In this study, the availability of Ni-Ba(Zr,Y)O3-delta (BZY) cermet for the anode of direct ammonia -fueled solid oxide fuel cells (SOFCs) is evaluated. In this device, the anodes need to be active for the catalytic ammonia decomposition as well as the electrochemical hydrogen oxidation. In the catalytic activity test, ammonia decomposes completely over Ni-BZY at ca. 600 degrees C, while higher temperature is required to accomplish the complete decomposition over the conventional SOFC anode of Ni yttria-stabilized zirconia cermet. The high activity of Ni-BZY is attributed to the high basicity of BZY and the high resistance to hydrogen poisoning effect. The electrochemical property of Ni-BZY anode is also evaluated with the anode-supported cell of Ni-BZYIBZYIPt at 600-700 degrees C with feeding ammonia or hydrogen as a fuel. Since the residence time of ammonia fuel in the thick Ni-BZY anode is long, the difference in the cell performance between two fuels is relatively small. Furthermore, it is proved that the steam concentration in the fuel strongly affects the cell performance. We find that this factor is important to satisfy the above mentioned requirements for the anode of direct ammonia-fueled SOFCs. Throughout this study, it is concluded that Ni-BZY cermet will be a promising anode. (C) 2017 Elsevier B.V. All rights reserved.