Total synthesis of a plocamium monoterpene marine natural product. Synthetic applications of bridgehead allylsilanes

摘要

A variety of polyhalogenated monoterpene natural products have been isolated from the red marine algae Plocamium sp. Violacene (1) and a related metabolite 2 Are representatives of this class of molecules. These Monoterpenes have been postulated to be involved in the Chemical defense of the algae and possess insect anti- Feedant properties.